Application Cases

Propane Dehydrogenation (PDH) to Propylene

Client:A listed refining and chemical company

Daily Treatment Capacity:500m³

Source of Treatment Solution:

Propane Dehydrogenation (PDH) is an essential chemical process that converts propane into propylene using a catalytic reaction.During operation, the catalyst gradually becomes deactivated as it is encapsulated by by-products formed in the reaction.To restore catalytic activity and maintain pore structure, steam purging is performed to remove these deposits.
The desorbed by-products — including unreacted heavy hydrocarbons, oligomers, and carbonaceous residues — are carried into the condensation system along with the steam.
As the temperature decreases, these substances condense and mix with cooling water, forming a stable oil–water emulsion.
The resulting oily wastewater is characterized by high oil concentration, strong emulsification, and fluctuating oil content, making it extremely difficult to treat using conventional separation methods.
The CASAIS Aggregation-Induced Separation process provides an effective, reliable, and fully physical solution to separate and recover oil from such challenging emulsified wastewater.

 

Process Comparison

 

Air flotation process

CASAIS process

Pharmaceutical additions

Adjust pH first,then add demulsification agent

None

Re-contamination

Generate a large amount of oil sludge hazardous waste and vOCs

None

Floor area

Sedimentation tanks, air flotation tanks, neutralization tanks, biochemical tanks

About 100m²

Labor cost

Three shifts,need to adjust pH and add chemicals manually

High automation

Treatment effect

High fluctuation of water discharge

Always stabilized at COD <500

Cost of tonnes of water

100%

46%

 

Treatment Effect

Liquid Inlet Index

COD(mg/L)

SS(mg/L)

38000-65000

<200

Liquid Output Index

COD(mg/L)

SS(mg/L)

<500

<30

 

Inlet and outlet water effect

Process operation sampling inspection record